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ChemInform Abstract: Polynuclear Copper(I) Complexes with Chelating Bis- and Tris-N-heterocyclic Carbene Ligands: Catalytic Activity in Nitrene and Carbene Transfer Reactions.

✍ Scribed by Cristina Tubaro; Andrea Biffis; Riccardo Gava; Elena Scattolin; Andrea Volpe; Marino Basato; M. Mar Diaz-Requejo; Pedro J. Perez

Book ID
112047076
Publisher
John Wiley and Sons
Year
2012
Weight
33 KB
Volume
43
Category
Article
ISSN
0931-7597

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Polynuclear Copper(I) Complexes with Che
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## Abstract The mononuclear cationic Rh^I^ complexes [Rh(cod)(mdd)]^+^X^−^ and [Rh(CO)~2~(mdd)]^+^X^−^ (X = BPh~4~, PF~6~) containing the chelating bidentate __N__‐heterocyclic carbene ligand 1,1′‐methylene‐3,3′‐dimethyldiimidazoline‐2,2′‐diylidene (mdd) have been synthesised and spectroscopically