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Elevated Catalytic Activity of Ruthenium(II)-Porphyrin-Catalyzed Carbene/Nitrene Transfer and Insertion Reactions with N-Heterocyclic Carbene Ligands

✍ Scribed by Chan, Ka-Ho; Guan, Xiangguo; Lo, Vanessa Kar-Yan; Che, Chi-Ming


Book ID
121729204
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
525 KB
Volume
53
Category
Article
ISSN
0044-8249

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## Abstract Di‐ and trinuclear complexes of copper(I) bearing bis‐ or tris‐N‐heterocyclic carbene ligands have been prepared and evaluated as catalysts in nitrene transfer reactions from PhI=NTs to unsaturated and saturated substrates (olefin aziridination and C–H bond amidation) and carbene transf