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Symmetric electron transfer reactions of state-selected ions: H2+ + H2 → H2 + H2+(ν= 0–10)

✍ Scribed by S.Keith Cole; Tomas Baer; Paul M. Guyon; Thomas R. Govers

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
588 KB
Volume
109
Category
Article
ISSN
0009-2614

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✦ Synopsis

Total symmetric electron transfer cross secrions for state-selected Hz ions were measured for vibrational levels of the ion from u = 0 to 10 af a relative uanslational energy of 16 eV. The internal energ of the rz ions was selected by thresllold photoclccrron-photoion coincidence using pulsed synchrotron radiation from the AC0 storage ring at Orsay. The relntive cross sections agree very well with the recent c;tlcuhtions of Lee zmd DePristo using a senklassicaf cner_~~ conserving trajectory approach with an accurate diabatic interaction potential between the ion and neutral diatoms.

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