Total symmetric electron transfer cross secrions for state-selected Hz ions were measured for vibrational levels of the ion from u = 0 to 10 af a relative uanslational energy of 16 eV. The internal energ of the rz ions was selected by thresllold photoclccrron-photoion coincidence using pulsed synchr
A State-selected study of the symmetric charge transfer reaction H2+ + H2
โ Scribed by C.L. Liao; C.X. Liao; C.Y. Ng
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 459 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
We have measured the relative total charge transfer cross sections of Hi + Hz as a function of the vibrational state of Hf, ub = 04.
using the crossed ion-neutral beam and high-resolution photoionization methods. The experimental results obtained at a center-of-mass collisional energy of 22.5 eV are found to be in excellent agreement with a recent theoretical study.
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A three-dimensional quantum-mechanical study of the (Ar + Hz)+ system within the reactive infinite-order sudden approximation is presented. All four possible channels for chemical reaction and charge transfer were treated simultaneously. The various cross sections deviate by at most 50% from recent
Product angular and velocity distributions for vibrationally state-selected ion-neutral reactions are measured wrth a new technique that uses resonantly enhanced multiphoton ionization and impulsive acceleration of reactant ions to achieve crossed-beam scattermg conditions in a single molecular beam