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Switching from the Myers reaction to a new thermal cyclization mode in enyne-allenes

✍ Scribed by Michael Schmittel; Marc Strittmatter; Susanne Kiau


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
226 KB
Volume
36
Category
Article
ISSN
0040-4039

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Ring Strain Effects in Enyne-Allene Ther
✍ Michael Schmittel; Jens-Peter Steffen; Dominik Auer; Michael Maywald πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 485 KB

The mode of the thermal cyclization of enyne-allenes 1 depends on ring strain effects: when the ene functionality is part of a benzene, cyclohexene or cycloheptene ring the novel C2-C6biradicrd cyclization is observed, while when it is part of a cyclopentene ring the Myers-Saito cycloaromatization i