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Switchable 2,2,2-Trifluoroethylation and gem -Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane

โœ Scribed by Wu, Guojiao; Deng, Yifan; Wu, Chaoqiang; Wang, Xi; Zhang, Yan; Wang, Jianbo

Book ID
124094098
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
246 KB
Volume
2014
Category
Article
ISSN
1434-193X

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โœ Georges Diderich ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 569 KB

Szinzmavy. The rates of the acid-catalysetl hydrolysis < I f a serics of hryi-2,2,2-trifluorocliazocthanes Ia-d havc been mcasured in dioxan/\vatcr/HC104. Thc results arc well corrclatetl with the Hanznzett equation when up substituent constants are used ( @ = -1.74 and er, = -1.75). Kinetic solven