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Swelling of a mesostructured zirconium oxide film

✍ Scribed by M.J. Henderson; A.R. Rennie; A.M. Hawley; J.W. White

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 149 KB
Volume: 385-386
Category: Article
ISSN: 0921-4526
DOI: 10.1016/j.physb.2006.05.305

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✦ Synopsis

The structural changes that cause the change in interlayer spacing of a surfactant-templated zirconium oxide film have been studied using neutron diffractometry. We report that the film after drying on a glass substrate swells slightly through the addition of benzene by up to 4 A ˚on a lattice parameter of about 36 A ˚. The (0 0 1) and (0 0 2) diffraction peak widths, positions and areas of a swollen film were monitored as a function of benzene desorption. Disorder of the lamellar mesophase is considered as a cause of the observed effects on the diffraction signals.

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