Suzuki—Miyaura Cross-Coupling Reactions of Benzyl Halides with Potassium Aryltrifluoroborates.
✍ Scribed by Gary A. Molander; Maxwell D. Elia
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 31 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract A general palladium‐catalyzed carbonylative cross‐coupling reaction of benzyl chlorides with potassium aryltrifluoroborates in water has been developed. Applying this improved methodology 16 different 1,2‐diarylethanones have been synthesized in 40–89% yield.
## Abstract Various benzyl halides are converted into diarylethanones in the presence of carbon monoxide using different aryl trifluoroborates.