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Palladium-Catalyzed Carbonylative Suzuki Coupling of Benzyl Halides with Potassium Aryltrifluoroborates in Aqueous Media

✍ Scribed by Xiao-Feng Wu; Helfried Neumann; Matthias Beller

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 173 KB
Volume: 353
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000804

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✦ Synopsis

Abstract

A general palladium‐catalyzed carbonylative cross‐coupling reaction of benzyl chlorides with potassium aryltrifluoroborates in water has been developed. Applying this improved methodology 16 different 1,2‐diarylethanones have been synthesized in 40–89% yield.

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