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Sustainable Epoxidation of Electron-Poor Olefins with Hydrogen Peroxide in Ionic Liquids and Recovery of the Products with Supercritical CO2

✍ Scribed by Olga Bortolini; Sandro Campestrini; Valeria Conte; Giancarlo Fantin; Marco Fogagnolo; Silvia Maietti


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
115 KB
Volume
2003
Category
Article
ISSN
1434-193X

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Guanidinium-Based Phosphotungstates and
✍ Loubna Gharnati; Olaf Walter; Ulrich Arnold; Manfred DΓΆring πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 434 KB

## Abstract Several penta‐ and hexaalkylated guanidinium‐based ionic liquids (GILs) were tested as solvents for the epoxidation of cyclooctene using the Venturello catalyst, [(C~8~H~17~)~3~N(CH~3~)]~3~[PO~4~{WO(O~2~)~2~}~4~], and hydrogen peroxide as the oxidant. Epoxide yields were obtained in a b