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Sustainable Epoxidation of Electron-Poor Olefins with Hydrogen Peroxide in Ionic Liquids and Recovery of the Products with Supercritical CO2.

✍ Scribed by Olga Bortolini; Sandro Campestrini; Valeria Conte; Giancarlo Fantin; Marco Fogagnolo; Silvia Maietti


Publisher
John Wiley and Sons
Year
2004
Weight
91 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract Several penta‐ and hexaalkylated guanidinium‐based ionic liquids (GILs) were tested as solvents for the epoxidation of cyclooctene using the Venturello catalyst, [(C~8~H~17~)~3~N(CH~3~)]~3~[PO~4~{WO(O~2~)~2~}~4~], and hydrogen peroxide as the oxidant. Epoxide yields were obtained in a b