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Surprising synthesis and reactivity of an acidic hydroxyphosphorane

โœ Scribed by Segall, Yoffi; Granoth, Itshak


Book ID
126278135
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
251 KB
Volume
101
Category
Article
ISSN
0002-7863

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Nitrodiazoacetic acid was prepared and its structure determined by tow temperature X-ray crystallography. There is good agreement between the experimentally determined structure and that calculated at the ab initio rhf13-21G level of theory. The acid is stable in neat trtfluoroacetic acid and less s