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Synthesis, structure, and reactivity of an organogermanium Lewis acid

✍ Scribed by Denmark, Scott E.; Jacobs, Robert T.; Dai-Ho, Ginny; Wilson, Scott


Book ID
126268078
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
612 KB
Volume
9
Category
Article
ISSN
0276-7333

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Nitrodiazoacetic acid was prepared and its structure determined by tow temperature X-ray crystallography. There is good agreement between the experimentally determined structure and that calculated at the ab initio rhf13-21G level of theory. The acid is stable in neat trtfluoroacetic acid and less s