Surface modification of active metals through atom transfer radical polymerization grafting of acrylics
β Scribed by Rachel Gong; Shane Maclaughlin; Shiping Zhu
- Book ID
- 108060579
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 772 KB
- Volume
- 254
- Category
- Article
- ISSN
- 0169-4332
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π SIMILAR VOLUMES
## Abstract Atom transfer radical polymerization (ATRP) was applied to the homopolymerization of glycidyl acrylate (GA). This functionalized monomer can be polymerized to high conversions and high molecular weights using halogenated initiators and CuBr/4,4β²βbis(5βnonyl)β2,2β²βbipyridine (dNbipy) as
The application of atom transfer radical polymerization (ATRP) to the homopolymerization of 2-hydroxyethyl acrylate, a functional monomer, is reported. The polymerizations exhibit first-order kinetics, and molecular weights increase linearly with conversion. Polydispersities remain low throughout th