𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polymerization of acrylates by atom transfer radical polymerization. Homopolymerization of glycidyl acrylate

✍ Scribed by Krzysztof Matyjaszewski; Simion Coca; Christina B. Jasieczek

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
350 KB
Volume
198
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Atom transfer radical polymerization (ATRP) was applied to the homopolymerization of glycidyl acrylate (GA). This functionalized monomer can be polymerized to high conversions and high molecular weights using halogenated initiators and CuBr/4,4′‐bis(5‐nonyl)‐2,2′‐bipyridine (dNbipy) as the catalyst. The polymerizations exhibit first order kinetics and molecular weights increase linearly with conversion. The MΜ„~n~ of the products is controlled by the ratio Ξ”[M]~0~/[I]~0~. The polymers obtained showed narrow molecular weight distributions, MΜ„~w~/MΜ„~n~ = 1.25.

πŸ“œ SIMILAR VOLUMES

Polymerization of acrylates by atom tran
Polymerization of acrylates by atom transfer radical polymerization. Homopolymerization of 2-hydroxyethyl acrylate
✍ Simion Coca; Christina B. Jasieczek; Kathryn L. Beers; Krzysztof Matyjaszewski πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 188 KB πŸ‘ 2 views

The application of atom transfer radical polymerization (ATRP) to the homopolymerization of 2-hydroxyethyl acrylate, a functional monomer, is reported. The polymerizations exhibit first-order kinetics, and molecular weights increase linearly with conversion. Polydispersities remain low throughout th

Atom-Transfer Radical Polymerization of
Atom-Transfer Radical Polymerization of 2-(N,N-Dimethylamino)ethyl Acrylate
✍ Faquan Zeng; Youqing Shen; Shiping Zhu πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 106 KB

## Abstract ATRP of 2‐(__N,N__‐dimethylamino)ethyl acrylate (DMAEA) was investigated using CuBr or CuCl with different multidentate ligands. The catalyst was found active for DMAEA polymerization when ligated with tris[2‐(__N,N__‐dimethylamino)ethyl]amine. Good control over molecular weight was ach