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Surface ion pairing between electrochemically treated glassy carbon and alkali metal ions in acetonitrile

✍ Scribed by Tsutomu Nagaoka; Toshikazu Fukunaga; Takashi Yoshino

Book ID
107793026
Publisher
Elsevier Science
Year
1987
Weight
256 KB
Volume
217
Category
Article
ISSN
0022-0728

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The electrochemical oxidation of the alkali‐metal ions Cs^βŠ•^, Rb^βŠ•^, K^βŠ•^, and Na^βŠ•^ appears to occur in liquid sulfur dioxide, but only at about + 4.7 V vs. SCE, as shown by studies on their AsF and PF salts for which other sources of the observed oxidation waves could be excluded. No evidence for