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Surface-initiated ring-opening polymerization of ϵ-caprolactone from the surface of PP film

✍ Scribed by Yuan Sui; Jingbo Zhao; Shenghua Gan; Hongchi Zhao; Wantai Yang


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
446 KB
Volume
105
Category
Article
ISSN
0021-8995

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Polymerization of 1-caprolactone had been investigated with cyclopentadienyl sodium as an initiator. The effects of reaction time, temperature, and concentration of the initiator on the yield and molecular weight of the polymer were discussed. It was shown that the high molecular weight of poly(1-ca

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The polymerization of caprolactone ( 1-CL) was initiated by yttrium triisopropoxide {Y(OP i r ) 3 }, bimetallic isopropoxide of yttrium and aluminum {Y[Al(OP i s ) 4 ] 3 }, yttrium and tin(II) {Y[Sn(OP i r ) 3 ] 3 }, and tin(II) and yttrium {Sn[Y(OP i r ) 4 ] 2 }, respectively. The polymerization wa