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Ring-opening polymerization of ε-caprolactone initiated by cyclopentadienyl sodium

✍ Scribed by Minglong Yuan; Chengdong Xiong; Xianmo Deng

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
116 KB
Volume
67
Category
Article
ISSN
0021-8995

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✦ Synopsis

Polymerization of 1-caprolactone had been investigated with cyclopentadienyl sodium as an initiator. The effects of reaction time, temperature, and concentration of the initiator on the yield and molecular weight of the polymer were discussed. It was shown that the high molecular weight of poly(1-caprolactone) (13 1 10 4 ) was obtained with cyclopentadienyl sodium initiator, and the mechanism of polymerization was also discussed.

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