Surface-Initiated Polymerizations in Aqueous Media: Effect of Initiator Density
β Scribed by Jones, D.M.; Brown, A.A.; Huck, W.T.S.
- Book ID
- 115521805
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 156 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0743-7463
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## Abstract **Summary:** We investigated the formation of thermoresponsive gold nanoparticle/poly(__N__βisopropylacrylamide) (AuNP/PNIPAAm) core/shell hybrid structures by surfaceβinitiated, atom transfer radical polymerization (SIβATRP) in aqueous media and the effect of crossβlinking on the therm
The free-radical polymerization behavior of 1-vinyl,2-pyrrolidone (NVP) was studied at low conversions, using capillary dilatometry. The aqueous media were kept at neutral pH and the studies were conducted isothermally, at 40 or 45Β°C. The azo-type initiators used were 4,4Π-azobis-4-cyanopentanoic ac