This letter reports the first observation of both surface enhanced Raman scatterins (SERS) and surface enhanced resonanre Raman scattering (SERRS) from the transition metal complex tris(2.2'-bipyridine)ruthcnium(iI), Ru(bpy)<+. adsorbed on a silver electrode from acetonitrile (ACN). The assignment o
Surface enhanced raman spectroscopy of the non-aqueous system silver/acetonitrile, KSCN
β Scribed by D.A. Guzonas; G.F. Atkinson; D.E. Irish
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 612 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The ~1 (CN) band of SCW in acetonitriie solvcnr has been observed, surface enhanced, at a silver electrode. Adsorption through the S of SCK is suggested. The changes of frequency and intensity with the change of electrode potenti& are reported. The u(CN) band of the solvent is also probably enhanced.
π SIMILAR VOLUMES
We have studled surface-enhanced Raman scattering from the rollowing non-aqueous elecwxhemxal systems: 0.05 M pyridme/O.l M LiCl/mclhanol/Ag ekrrode. 0.05 M pyridmc/O.l M LiCl/ethanol/Ag elecuode. and 0.05 M benzene/O.1 M LCl/edunol/Ag elects&. Each SERS band of pyri&ne is found to show ?wo &slincti
The study of the surface enhanced Raman spectroscopy (SERS) excitation profiles of 1,5-dimethylcytosine on metal colloids allows a more detailed determination of the behavior of the functional groups of this molecule in the adsorption process on the metal supports. Silver has shown its effectiveness