This letter reports the first observation of both surface enhanced Raman scatterins (SERS) and surface enhanced resonanre Raman scattering (SERRS) from the transition metal complex tris(2.2'-bipyridine)ruthcnium(iI), Ru(bpy)<+. adsorbed on a silver electrode from acetonitrile (ACN). The assignment o
Surface enhanced Raman scattering from tris (bipyridine) ruthenium (II) adsorbed on silver-modified p-GaAs
✍ Scribed by Y. Mo; H. von Känel; P. Wachter
- Book ID
- 103374409
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 240 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0038-1098
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SJZRS on silver sol has been demonstrated to be an attractive and simple spectroscopic tool for transition-metal complexes. The SERS spectra of [Cr(bpy),)3+ on Ag sol are more similar to the solution Raman spectra of [Fe(bpy)3]2' or [Ru(bpy)3]2' than to that of [Cr(bpy)~])+, which gives a strong hin
Enhanced Raman scattering has been observed from the hexacyanoferrate (II) and (III) ions adsorbed on Ag electrode surfaces. In the former case, five vibrational modes in the low-frequency range (214, 373,423,494 and 560 cm-') and four in the nitrilc-stretching region (2026,2067,2082 and 2122 cm-')
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