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Surface curvature effects on the NMR chemical shift for molecules trapped in microporous solids

✍ Scribed by Eric G. Derouane; Janos B. Nagy

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 319 KB
Volume: 137
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80896-5

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✦ Synopsis

It is shown that the chemical shifts characteristic of molecules trapped in zeolites ( '*'Xe, and "C for (CH,),N+ ions) correlate directly with the surface curvature effects influencing the physisorption (dispersion) energy. Pore size is the determining parameter and other factors have negligible effect.

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