Commercially pure titanium was anodized in an electrolytic solution that was dissolved calcium and phosphorus compounds in water, and an AOFCP (anodic titanium oxide film containing Ca and P) was formed. It was found that sodium P-glycerophosphate (P-GP) and calcium acetate (CA) were suitable for th
Surface characteristics and structure of anodic oxide films containing Ca and P on a titanium implant material
β Scribed by Zhu, Xiaolong ;Ong, Joo L. ;Kim, Sukyoung ;Kim, Kyohan
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 166 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0021-9304
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β¦ Synopsis
Abstract
An anodic oxide film that formed on titanium with a mixture of Ξ²βglycerophosphate sodium (Ξ²βGP) and calcium acetate was investigated. The anodic oxide had interconnected pores (ca. 1β2 ΞΌm in diameter) and intermediate roughness (0.60β1.50 ΞΌm). In addition, it contained a mixture of amorphous, anatase, and rutile oxides. With an increase in the anodizing voltage and/or concentration of calcium incorporated into the oxide, the degree of oxide crystallinity increased. However, with an increase in the concentration of Ξ²βGP, the degree of oxide crystallinity decreased. It was concluded that the surface roughness, oxide crystallinity, and surface composition of the anodic oxide were dependent on the voltage, current density, and concentration of the electrolyte. It was also concluded that the anodized surface could be optimized for maximum osseointegration. Β© 2002 John Wiley & Sons, Inc. J Biomed Mater Res 60: 333β338, 2002; DOI 10.1002/jbm.10105
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An anodic titanium oxide film containing Ca and P (AOFCP) was formed on commercially pure titanium which was anodized in an electrolytic solution of dissolved p-glycerophosphate (P-GP) and calcium acetate (CA). Hydroxyapatite (HA) crystals were precipitated by hydrothermally heating the AOFCP at 300
The passivating surface oxide on titanium is one of the elements considered in the explanation of the favorable biologic response of this metal in implant applications. In the present study, transmission electron microscopy was used to identify the crystal structure and morphology of the oxide film