Two novel complexes [Zn(phba) 2 (btp)] 2 (1) and [Cd(phba) 2 (btp)(H 2 O)] n (2) have been synthesized by using 1,3-bis(1,2,4-triazol-1yl)propane (btp) and 4-hydroxybenzoate (phba). 1 contains the neutral dimer Zn 2 (btp) 2 metallacycle, while 2 forms the one-dimensional zigzag chain structure. 1 an
✦ LIBER ✦
Supramolecular Structures Constructed by Connection of One-Dimensional Polymer Chains Through the Dimeric Water Clusters in Coordination Polymers of Pyromellitate Ligand
✍ Scribed by Gökhan Kaştaş, Tuğba Ak Aycan, Hümeyra Paşaoğlu, Can Kocabıyık, Bünyamin Karabulut
- Book ID
- 118802738
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 906 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1053-0495
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## Abstract Treatment of CuI with PhSCH~2~SPh in MeCN solution affords, by a self‐assembly reaction, the monodimensional metal–organic coordination polymer [Cu~4~I~4~{μ‐PhS~2~CH~2~SPh}~2~]__~n~__ (1), in which Cu~4~(μ^3^‐I)~4~ cluster units are linked by the dithioether ligand in a 1D necklace stru