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Supramolecular Chirality: Chiral hydrogen-bonded supermolecules from achiral molecular components

✍ Scribed by Mauricio Suárez; Neil Branda; Jean-Marie Lehn; André Decian; Jean Fischer

Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
589 KB
Volume
81
Category
Article
ISSN
0018-019X

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✦ Synopsis

Chiral supermolecules may be obtained from suitable achiral molecular constituents associated through a dissymmetrizing interaction mode. This is the case for the supermolecules I-IV formed by hydrogen-bonding association between the achiral complementary components la, b and Za,b,c. The crystal structures of the supermolecular pairs 1-111 and of the homochiral aggregate of two ternary supermolecules IV have been determined. The structural data are discussed.

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