Enantiomorphous monolayers of enantiopure formamides form on a graphite surface, while the racemic compound does not undergo a spontaneous resolution under similar conditions. This difference in the two-dimensional behavior has been studied by scanning tunneling microscopy (see image of the racemate
✦ LIBER ✦
Homo- and Heterochiral Supramolecular Tapes from Achiral, Enantiopure, and Racemic Promesogenic Formamides: Expression of Molecular Chirality in Two and Three Dimensions
✍ Scribed by Steven De Feyter; André Gesquière; Klaus Wurst; David B. Amabilino; Jaume Veciana; Frans C. De Schryver
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 255 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
Compounds 1 and 2 were prepared according to the published method. [15] The STM images were acquired in the variable current mode (constant height) under ambient conditions with the tip immersed in the liquid. For details see ref. [9].
📜 SIMILAR VOLUMES
Homo- and Heterochiral Supramolecular Ta
✍
Steven De Feyter; André Gesquière; Klaus Wurst; David B. Amabilino; Jaume Vecian
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
English
⚖ 254 KB
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