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Homo- and Heterochiral Supramolecular Tapes from Achiral, Enantiopure, and Racemic Promesogenic Formamides: Expression of Molecular Chirality in Two and Three Dimensions

✍ Scribed by Steven De Feyter; André Gesquière; Klaus Wurst; David B. Amabilino; Jaume Veciana; Frans C. De Schryver


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
255 KB
Volume
113
Category
Article
ISSN
0044-8249

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✦ Synopsis


Compounds 1 and 2 were prepared according to the published method. [15] The STM images were acquired in the variable current mode (constant height) under ambient conditions with the tip immersed in the liquid. For details see ref. [9].


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Homo- and Heterochiral Supramolecular Ta
✍ Steven De Feyter; André Gesquière; Klaus Wurst; David B. Amabilino; Jaume Vecian 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

Enantiomorphous monolayers of enantiopure formamides form on a graphite surface, while the racemic compound does not undergo a spontaneous resolution under similar conditions. This difference in the two-dimensional behavior has been studied by scanning tunneling microscopy (see image of the racemate