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Supramolecular Chemistry of Anionic Cobalt(III) Bis(dicarbollide) and Cyclotriveratrylene in the Solid State and the Gas Phase

✍ Scribed by Michaele J. Hardie; Colin L. Raston

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
185 KB
Volume
39
Category
Article
ISSN
0044-8249

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✦ Synopsis

Despite the fundamental role played by anionic species in many natural processes the supramolecular chemistry of anions has been one of the least explored aspects of supramolecular chemistry. While the neutral, isomeric icosahedral carboranes o, m, p-C 2 B 10 H 12 , for instance, are emerging as versatile components in supramolecular systems, forming hydrogen-bonded complexes [2] and host ± guest species with a range of host molecules and assemblies, [3±9] studies on the supramolecular chemistry of anionic carboranes, or indeed anionic boranes, are limited. The most significant example of the binding of a borane anion in a supramolecular system is that of the divalent anion [B 10 H 10 ] 2À which forms a host ± guest

[2] S.

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