Despite the fundamental role played by anionic species in many natural processes the supramolecular chemistry of anions has been one of the least explored aspects of supramolecular chemistry. While the neutral, isomeric icosahedral carboranes o, m, p-C 2 B 10 H 12 , for instance, are emerging as ve
Supramolecular Chemistry of Anionic Cobalt(III) Bis(dicarbollide) and Cyclotriveratrylene in the Solid State and the Gas Phase
✍ Scribed by Michaele J. Hardie; Colin L. Raston
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 185 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0044-8249
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processes has been described for the reactions of some halogen-1993). With respect to radical anions in the gas phase, a substituted carbene radical anions with the methyl ester of trifluoroacetic acid and dimethyl carbonate. The structural charac-more limited number of reports has appeared irrespec
Upon treating elemental sulfur with [AgSbF(6)], [AgAl(hfip)(4)], [AgAl(pftb)(4)] (hfip=OCH(CF(3))(2), pftb =OC(CF(3))(3)) the compounds [Ag(S(8))(2)][SbF(6)] (1), [AgS(8)][Al(hfip)(4)] (2), and [Ag(S(8))(2)](+)[[Al(pftb)(4)](-) (3) formed in SO(2) (1), CS(2) (2), or CH(2)Cl(2) (3). Compounds 1-3 wer