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Suppression of the harpooning mechanism in donor-bridge-acceptor systems by aza substitution in the bridge

✍ Scribed by Xavier Y. Lauteslager; Bas Wegewijs; Jan W. Verhoeven; Albert M. Brouwer


Book ID
103992796
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
1022 KB
Volume
98
Category
Article
ISSN
1010-6030

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Photoinduced electron-transfer rates are reported for two pairs of rigid bichromophoric molecules 1(6)/2(6) and 1(8)/2( 8). In the first pair electron donor and acceptor are separated by six, in the second pair by eight, carbon-carbon o bonds. While these o bonds provide an all-trans coupling path