Through-bond modulation of intramolecula
Through-bond modulation of intramolecular electron transfer in rigidly linked donor-acceptor systems
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James M. Lawson; Donald C. Craig; Michael N. Paddon-Row; Jan Kroon; Jan W. Verho
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Article
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1989
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Elsevier Science
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English
⚖ 447 KB
Photoinduced electron transfer rates are reported for a pair of rigid bichromophoric molecules, l(8) and 3( 8), in a variety of solvents. It was found that intramolecular electron transfer in l( ) is up to five times faster than in 3( 8). X-ray crystallography revealed that the cyclopentyl ring atta