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Experimental Verification of the Through-Bond Mechanisms of Electron Transfer in Bridged Donor−Acceptor Complexes

✍ Scribed by Pullen, Stuart H.; Edington, Maurice D.; Studer-Martinez, Shannon L.; Simon, John D.; Staab, Heinz A.


Book ID
126964137
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
47 KB
Volume
103
Category
Article
ISSN
1089-5639

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Photoinduced electron transfer rates are reported for a pair of rigid bichromophoric molecules, l(8) and 3( 8), in a variety of solvents. It was found that intramolecular electron transfer in l( ) is up to five times faster than in 3( 8). X-ray crystallography revealed that the cyclopentyl ring atta