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Suppression of high-field (T0-S) chemically induced nuclear spin polarization (CIDNP) by successive trapping of radicals. Persistence of low-field (T1-S) CIDNP

✍ Scribed by Garst, John F.; Barton, Franklin E.; Morris, John I.

Book ID: 127286252
Publisher: American Chemical Society
Year: 1971
Tongue: English
Weight: 370 KB
Volume: 93
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00746a047

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✍ F.J. Adrian 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 454 KB

It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount