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Supported Ziegler–Natta catalyst for ethylene polymerization: Novel data on the effect of polymerization temperature on the number of active centers and propagation rate constant

✍ Scribed by Barabanov, Artem A.; Zakharov, Vladimir A.


Book ID
121424152
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
388 KB
Volume
45
Category
Article
ISSN
1566-7367

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Ethylene Polymerization over Homogeneous
✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u