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Determination of the number of propagation centers and the propagation rate constant for ethylene polymerization on supported titanium catalysts

✍ Scribed by Zakharov, V. A. ;Chumayevskii, N. B. ;Makhtarulin, S. I. ;Bukatov, G. D. ;Yermakov, Yu I.


Book ID
112682725
Publisher
Springer
Year
1975
Tongue
English
Weight
229 KB
Volume
2
Category
Article
ISSN
0133-1736

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πŸ“œ SIMILAR VOLUMES


Ethylene Polymerization over Homogeneous
✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 175 KB

## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u

Number of active centers and propagation
✍ Gennadii D. Bukatov; Valerii S. Goncharov; Vladimir A. Zakharov πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

Polymerization inhibition with radioactive carbon monoxide was used to determine the number of active centers (C,) and the propagation rate constant (k,) in the isospecific polymerization of propene with the catalytic system TiCl,/diisobutyl phthalate/MgC1,-A1Et,-PhSi(OEt)3. The presence of hydrogen