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Supported liquid membrane separation of amine and amino acid derivatives with chiral esters of phosphoric acids as carriers

✍ Scribed by Paweł Dżygiel; Piotr Wieczorek; Paweł Kafarski

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
370 KB
Volume
26
Category
Article
ISSN
1615-9306

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✦ Synopsis

Supported liquid membrane separation of amine and amino acid derivatives with chiral esters of phosphoric acids as carriers

Studies on the possible use of phosphate and phosphonate esters bearing chiral menthol or nopol moieties as carriers for the transport of amines, amino acids, and amino acid esters through supported liquid membranes (SLM) are presented. Additionally, the enantioselectivity of the SLM transport of alkyl esters of aromatic amino acids and a non-protein amino acid was also evaluated. It could be concluded that the extent of transport strongly depends on the hydrophobicity of the amino compound. Moreover, the carrier structure also influences the transport of those compounds through SLM: chiral phosphate and phosphonate esters appear to be poor or moderate carriers for enantioselective SLM transport of amino acids and their esters. The transport efficiency and selectivity is strongly dependent on the structure of both the transported compounds and the carrier. However, no meaningful relationship exists between these structural features and transportation or enantioselectivity.

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