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Supported Aqueous-Phase Palladium Catalysts for the Reaction of Allylic Substitution: Toward an Understanding of the Catalytic System

✍ Scribed by dos Santos, Sylvia; Tong, Yuye; Quignard, Françoise; Choplin, Agnès; Sinou, Denis; Dutasta, Jean Pierre


Book ID
120401896
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
240 KB
Volume
17
Category
Article
ISSN
0276-7333

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Palladium(0)-catalyzed substitution of a
✍ Silvana Sigismondi; Denis Sinou 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 665 KB

The regioselectivity of the reaction of ethyl acetoacetate on allylic carbonate in the presence of a catalyst prepared from Pd(OAc), and P(C,H,-m-SO,Na), (or tppts) is not affected by the ratio Pd(OAc),/tppts, the nature of the nitrile, the relative amounts of water and nitrile or the temperature of