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Influence of the Reaction Conditions and Catalytic Properties on the Liquid-Phase Hydrodechlorination of Chlorobenzene over Palladium-Supported Catalysts: Activity and Deactivation

✍ Scribed by M.A. Aramendı́a; V. Boráu; I.M. Garcı́a; C. Jiménez; F. Lafont; A. Marinas; J.M. Marinas; F.J. Urbano

Book ID
112255863
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
85 KB
Volume
187
Category
Article
ISSN
0021-9517

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Liquid-phase hydrodechlorination of chlo
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The influence of HCl production and NaOH addition on catalytic activity in the liquid-phase hydrodechlorination of chlorobenzene over palladium-supported catalysts was studied. The rate of dehydrochlorination reaction falls with time owing to the poisoning effect of HCl gradually formed as by-produc

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The catalytic hydrodechlorination of chlorobenzene with NirC, PdrC and Ni Pd rC in ethanol was studied with 2 D 98 2 13 Ä 1 4 Ž . and C H NMR. Two dechlorination routes of this reaction ionic and free-radical are suggested depending upon the nature of the active hydrogen species. At the same time t