The mutual destabilization of LiAlH 4 and MgH 2 in the reactive hydride composite LiAlH 4 eMgH 2 is attributed to the formation of intermediate compounds, including LieMg and MgeAl alloys, upon dehydrogenation. TiF 3 was doped into the composite for promoting this interaction and thus enhancing the
β¦ LIBER β¦
Superior hydrogen storage kinetics of MgH2 nanoparticles doped with TiF3
β Scribed by L. Xie; Y. Liu; Y.T. Wang; J. Zheng; X.G. Li
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 808 KB
- Volume
- 55
- Category
- Article
- ISSN
- 1359-6454
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TiF 3 shows a superior catalytic effect over TiCl 3 in improving the hydrogen sorption kinetics of MgH 2 . Combined phase analysis and microstructure characterization suggest that both titanium halide additives react with host MgH 2 in a similar way. However, systematic X-ray photoelectron spectrosc