Superelectrophiles in the synthesis of condensation monomers and polymers
โ Scribed by Rusanov, A L; Chebotarev, V P; Lovkov, S S
- Book ID
- 127151419
- Publisher
- Royal Society of Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 137 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0036-021X
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๐ SIMILAR VOLUMES
## Abstract A convenient and practical synthesis of trimethylamine acrylimide, **1**, starting from 1, 1, 1โtrimethylhydrazinium __p__โtoluenesulfonate, **3**, and 3โchloropropionyl chloride is described. The intermediate, trimethylamine 3โchloropropionimide, **2**, is easily transformed into **1**
The use of P205 for promoting the tritiation of various monomers and polymers has been investigated. Methyl methacrylate and vinyl acetate may be labelled at ambient temperatures by this procedure which is also applicable to labelling polystyrene and poly(~t-methylstyrene). Exchange labelling of pol