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Sulphur substituted organotin compounds. Part 6. Reactions of mercaptomethyltin compounds with arenesulphenyl chlorides

✍ Scribed by James L. Wardell; Robin D. Taylor

Book ID
104220702
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
115 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reactions between PhaSnCHaSAr and 2-NOaCsHsSCf lead to the formation of 2-(ArSCHa)-6-NOaC,j&SSCslh,N02-2 via the [2,3] sigmatropic rearrangement of the S-arylthiosulphonium ylides EHa-S(Ar)SCaHsNOa-2. Gassman and Miura2 recently reported, in this Journal, reactions between arenesulphenyl chlorides and (methylthiomethyl)trimethylsilane, equation (1). Of particular interest was the compound X -u

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