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Sulphur-substituted organometallic compounds. Part V. Reactions of sulphidomethyl-platinum and palladium compounds with electrophilic reagents

✍ Scribed by Helen D. McPherson; James L. Wardell

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 150 KB
Volume: 35
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)93396-6

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✦ Synopsis

Reports [ 1 ] have been made recently by Japanese workers on the preparation and structures of sulphi domethyl-platinum and palladium complexes, including those in which the RSCH, unit is acting as a monodentate l&and, e.g. in (PPh3)2M(CH2SMe)Cl (M = Pt and Pd) (I), and as a bidentate l&and, e.g. in [(PPh3)2MCH2SMe] PF,, (PPh,)Pd(CH,SMe)Cl(II) and [(PPh,)Pt(p-CH,SMe)Cl] *.

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