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Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

✍ Scribed by R.W. Carlson; M.S. Anderson; R.E. Johnson; M.B. Schulman; A.H. Yavrouian


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
155 KB
Volume
157
Category
Article
ISSN
0019-1035

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✦ Synopsis


Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H 2 SO 4 β€’ nH 2 O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S x , sulfur dioxide SO 2 , hydrogen sulfide H 2 S, and H 2 SO 4 β€’ nH 2 O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G Mixture (SO 2- 4 ) = f Sulfur (r 0 /r) Ξ² G 1 molecules (100 eV) -1 , where f Sulfur is the sulfur weight fraction, r is the grain radius, r 0 = 50 Β΅m, Ξ² β‰ˆ1.9, and G 1 = 0.4 Β± 0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H 2 SO 4 ) N(S) > N(SO 2 ) > N(H 2 S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H 2 SO 4 is Ο„ (-S) = 120(r/r 0 ) Ξ² years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.


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