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Sulfur Oxygenation of [Ni(btdt)2]2– by Aerial Oxidation under Ambient Conditions – Syntheses, Crystal Structures, and Properties of [Bu4N]2[Ni(btdt)2] and [Bu4N]2­[Ni(btdtO2)2]·H2O ({btdt}2– = 2,1,3-Benzenethiadiazole-5,6-dithiolate)

✍ Scribed by Ramababu Bolligarla; Samar K. Das


Book ID
112082359
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
838 KB
Volume
2012
Category
Article
ISSN
1434-1948

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Synthesis and crystal structure of [Bu4N
✍ Yvonne S. J. Veldhuizen; Nora Veldman; Anthony L. Spek; Jaap G. Haasnoot; Jan Re 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 222 KB

## Abstract [Bu~4~N][Ni(mdt)~2~] (H~2~mdt = 2__H__‐1,3‐dithiole‐4,5‐dithiol) has been prepared in a three‐step synthesis from [Bu~4~N]~2~[Zn(dmit)~2~] (H~2~dmit = 2‐thione‐1,3‐dithiole‐4,5‐dithiol). The crystal structure is reported which shows that the Ni(mdt)~2~ anion is distorted significantly f