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Sulfur-mediated radical cyclisation reactions on solid support

โœ Scribed by David C Harrowven; Peter J May; Mark Bradley

Book ID
104252695
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
191 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.

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