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Sulfur cleavage of a phosphorus-phosphorus double bond

✍ Scribed by Alan H. Cowley; Marek Pakulski

Book ID
104233548
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
68 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cleavage of the phosphorus-phosphorus double bond takes place when the diphosphene, (2,4,6-(t_Bu)3C6H2P)2, is treated with excess sulfur in the presence of DBU (1,5-diazabicyclo[5*4.O]undec-5-ene).

📜 SIMILAR VOLUMES

Reductive cleavage of the halogen–phosph
Reductive cleavage of the halogen–phosphorus and sulfur–phosphorus bonds with alkali metals
✍ Marek Stankiewicz; Jacek Nycz; Janusz Rachon 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB

## Abstract The reduction of thiophosphorus acid chlorides with alkali metals (Na, K) in liq. NH~3~/THF solution, potassium anthracenide, and potassium naphthalenide was investigated. It was found that these types of phosphorus compounds easily undergo reduction to >PS^−^ anions. It was also demon