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REDUCTIVE CLEAVAGE OF THE HALOGEN-PHOSPHORUS, OXYGEN-PHOSPHORUS AND PHOSPHORUS-PHOSPHORUS BONDS WITH ALKALI METALS

✍ Scribed by Nycz, Jacek; Rachon, Janusz

Book ID
118244791
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
769 KB
Volume
161
Category
Article
ISSN
1042-6507

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Reductive cleavage of the halogen–phosph
Reductive cleavage of the halogen–phosphorus and sulfur–phosphorus bonds with alkali metals
✍ Marek Stankiewicz; Jacek Nycz; Janusz Rachon 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB

## Abstract The reduction of thiophosphorus acid chlorides with alkali metals (Na, K) in liq. NH~3~/THF solution, potassium anthracenide, and potassium naphthalenide was investigated. It was found that these types of phosphorus compounds easily undergo reduction to >PS^−^ anions. It was also demon