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Sulfonation with Sulfur Trioxide - High Boiling Alkylated Benzene

✍ Scribed by Gilbert, Everett; Veldhuis, Benjamin

Book ID
126297538
Publisher
American Chemical Society
Year
1958
Weight
582 KB
Volume
50
Category
Article
ISSN
0019-7866

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## Abstract Sulfonation of norbornene 1 with the SO~3~‐dioxane complex affords the β‐sultone 2, which rearranges at room temperature to the γ‐sultone 3. Reaction of 1 with 2 equiv of SO~3~‐nitromethane yields the carbyl sulfate 4. Carbocations are __not__ involved in the formation of either the β‐s