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Sulfonation of 1-butenes with sulfur trioxide

✍ Scribed by Robbins, M. D.; Broaddus, C. D.

Book ID
120778725
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
425 KB
Volume
39
Category
Article
ISSN
0022-3263

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## Abstract Sulfonation of norbornene 1 with the SO~3~‐dioxane complex affords the β‐sultone 2, which rearranges at room temperature to the γ‐sultone 3. Reaction of 1 with 2 equiv of SO~3~‐nitromethane yields the carbyl sulfate 4. Carbocations are __not__ involved in the formation of either the β‐s