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Sulfonated Xantphos Ligand and Methylated Cyclodextrin: A Winning Combination for Rhodium-Catalyzed Hydroformylation of Higher Olefins in Aqueous Medium

✍ Scribed by Leclercq, Loïc; Hapiot, Frédéric; Tilloy, Sébastien; Ramkisoensing, Kevita; Reek, Joost N. H.; van Leeuwen, Piet W. N. M.; Monflier, Eric

Book ID
126450881
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
146 KB
Volume
24
Category
Article
ISSN
0276-7333

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Water-Soluble Triphenylphosphane-3,3′,3′′-tricarboxylate (m-TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium-Catalyzed Hydroformylation of Higher Olefins
✍ Sébastien Tilloy; Emilie Genin; Frédéric Hapiot; David Landy; Sophie Fourmentin; 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 1 views

## Abstract The methylated cyclodextrins/__m__‐TPPTC [tris(__m__‐carboxyphenyl)phosphane trilithium salt] couples proved to be more efficient than the well‐known methylated cyclodextrins/TPPTS [tris(__m__‐sulfonatophenyl)phosphane trisodium salt] systems in terms of activities and selectivities to