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Sulfonate protecting groups. Regioselective O-sulfonylation of myo-inositol orthoesters

โœ Scribed by Kana M Sureshan; Mysore S Shashidhar


Book ID
104230435
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
81 KB
Volume
42
Category
Article
ISSN
0040-4039

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Corrigendum to โ€œSulfonate protecting gro
Regioselective O-acylation of myo-inosit
โœ K.M Sureshan; M.S Shashidhar ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 95 KB

An efficient and general method for the preparation of 2-O-acylated derivatives of myo-inositol 1,3,5-orthoesters via isomerization of the corresponding 4(6)-O-acylated derivatives has been described. The isomerization involves a novel 1(axial)โ†’3(equatorial) intramolecular acyl migration assisted by