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“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

✍ Scribed by Valdivia, Victoria; Fernández, Inmaculada; Khiar, Noureddine


Book ID
126507615
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
357 KB
Volume
12
Category
Article
ISSN
1477-0520

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9